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A Xanthene‐Based Mono‐Anionic PON Ligand: Exploiting a Bulky, Electronically Unsymmetrical Donor in Main Group Chemistry

The synthesis of a novel mono‐anionic phosphino‐amide ligand based on a xanthene backbone is reported, togetherr with the corresponding Ga(I) complex, (PON)Ga (PON = 4‐(di(2,4,6‐trimethylphenyl)phosphino)‐5‐(2,6‐diisopropylanilido)‐2,7‐di‐tert‐butyl‐9,9‐dimethylxanthene). The solid‐state structure o...

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Detalles Bibliográficos
Autores principales: Zheng, Xiongfei, Heilmann, Andreas, McManus, Caitilín, Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898390/
https://www.ncbi.nlm.nih.gov/pubmed/33200850
http://dx.doi.org/10.1002/chem.202004741