Cargando…

Efficient Suppression of Chain Transfer and Branching via C (s)‐Type Shielding in a Neutral Nickel(II) Catalyst

An effective shielding of both apical positions of a neutral Ni(II) active site is achieved by dibenzosuberyl groups, both attached via the same donors’ N‐aryl group in a C (s)‐type arrangement. The key aniline building block is accessible in a single step from commercially available dibenzosuberol....

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Chaoqun, Kang, Xiaohui, Dai, Shengyu, Cui, Fengchao, Li, Yunqi, Mu, Hongliang, Mecking, Stefan, Jian, Zhongbao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898505/
https://www.ncbi.nlm.nih.gov/pubmed/33200862
http://dx.doi.org/10.1002/anie.202013069