Intramolecular Halo Stabilization of Silyl Cations—Silylated Halonium‐ and Bis‐Halo‐Substituted Siliconium Borates

The stabilizing neighboring effect of halo substituents on silyl cations was tested for a series of peri‐halo substituted acenaphthyl‐based silyl cations 3. The chloro‐ (3 b), bromo‐ (3 c), and iodo‐ (3 d) stabilized cations were synthesized by the Corey protocol. Structural and NMR spectroscopic in...

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Detalles Bibliográficos
Autores principales: Merk, Anastasia, Bührmann, Lukas, Kordts, Natalie, Görtemaker, Katharina, Schmidtmann, Marc, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898513/
https://www.ncbi.nlm.nih.gov/pubmed/33184927
http://dx.doi.org/10.1002/chem.202004838

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898513/
https://www.ncbi.nlm.nih.gov/pubmed/33184927
http://dx.doi.org/10.1002/chem.202004838

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