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Easy Access to Enantiomerically Pure Heterocyclic Silicon‐Chiral Phosphonium Cations and the Matched/Mismatched Case of Dihydrogen Release

Phosphonium ions are widely used in preparative organic synthesis and catalysis. The provision of new types of cations that contain both functional and chiral information is a major synthetic challenge and can open up new horizons in asymmetric cation‐directed and Lewis acid catalysis. We discovered...

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Detalles Bibliográficos
Autores principales: Fontana, Nicolò, Espinosa‐Jalapa, Noel Angel, Seidl, Michael, Bauer, Jonathan O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898527/
https://www.ncbi.nlm.nih.gov/pubmed/33264430
http://dx.doi.org/10.1002/chem.202005171