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Carbenaporphyrins: No Longer Missing Ligands in N‐Heterocyclic Carbene Chemistry
The synthesis of an NHC‐containing porphyrinoid ligand is presented. The formally antiaromatic 20 πe(−) macrocyclic framework can be obtained via a 1,3‐dipolar cycloaddition (“click‐reaction”) to form two triazole moieties which were alkylated to the respective triazolium macrocycle. Deprotonation o...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898644/ https://www.ncbi.nlm.nih.gov/pubmed/33078891 http://dx.doi.org/10.1002/anie.202013434 |