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Activation of CS(2) and CO(2) by Silylium Cations
The hydride‐bridged silylium cation [Et(3)Si−H−SiEt(3)](+), stabilized by the weakly coordinating [Me(3)NB(12)Cl(11)](−) anion, undergoes, in the presence of excess silane, a series of unexpected consecutive reactions with the valence‐isoelectronic molecules CS(2) and CO(2). The final products of th...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898686/ https://www.ncbi.nlm.nih.gov/pubmed/33215771 http://dx.doi.org/10.1002/chem.202005003 |