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Activation of CS(2) and CO(2) by Silylium Cations

The hydride‐bridged silylium cation [Et(3)Si−H−SiEt(3)](+), stabilized by the weakly coordinating [Me(3)NB(12)Cl(11)](−) anion, undergoes, in the presence of excess silane, a series of unexpected consecutive reactions with the valence‐isoelectronic molecules CS(2) and CO(2). The final products of th...

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Detalles Bibliográficos
Autores principales:	Jenne, Carsten, Nierstenhöfer, Marc C., van Lessen, Valentin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898686/ https://www.ncbi.nlm.nih.gov/pubmed/33215771 http://dx.doi.org/10.1002/chem.202005003

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