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CO‐Induced Dinitrogen Fixation and Cleavage Mediated by Boron
The boron atoms react with carbon monoxide and dinitrogen forming the end‐on bonded NNBCO complex in solid neon or in nitrogen matrices. The NNBCO complex rearranges to the (η (2)‐N(2))BCO isomer with a more activated side‐on bonded dinitrogen ligand upon visible light excitation. (η (2)‐N(2))BCO an...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898689/ https://www.ncbi.nlm.nih.gov/pubmed/32990332 http://dx.doi.org/10.1002/chem.202004357 |