Cargando…

CO‐Induced Dinitrogen Fixation and Cleavage Mediated by Boron

The boron atoms react with carbon monoxide and dinitrogen forming the end‐on bonded NNBCO complex in solid neon or in nitrogen matrices. The NNBCO complex rearranges to the (η (2)‐N(2))BCO isomer with a more activated side‐on bonded dinitrogen ligand upon visible light excitation. (η (2)‐N(2))BCO an...

Descripción completa

Detalles Bibliográficos
Autores principales:	Deng, Guohai, Pan, Sudip, Dong, Xuelin, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898689/ https://www.ncbi.nlm.nih.gov/pubmed/32990332 http://dx.doi.org/10.1002/chem.202004357

Ejemplares similares

Side‐On Bonded Beryllium Dinitrogen Complexes
por: Deng, Guohai, et al.
Publicado: (2020)

Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide
por: Deng, Guohai, et al.
Publicado: (2020)

Octa-coordinated alkaline earth metal–dinitrogen complexes M(N(2))(8) (M=Ca, Sr, Ba)
por: Wang, Qian, et al.
Publicado: (2019)

Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)(8) (TM=Zr, Hf) and Ti(CO)(7)
por: Deng, Guohai, et al.
Publicado: (2020)

Generation and Identification of the Linear OCBNO and OBNCO Molecules with 24 Valence Electrons
por: Deng, Guohai, et al.
Publicado: (2020)

Octacarbonyl Ion Complexes of Actinides [An(CO)(8)](+/−) (An=Th, U) and the Role of f Orbitals in Metal–Ligand Bonding
por: Chi, Chaoxian, et al.
Publicado: (2019)

Generation and Characterization of the C(3)O(2) (−) Anion with an Unexpected Unsymmetrical Structure
por: Wang, Lina, et al.
Publicado: (2021)

Transition‐Metal Chemistry of Alkaline‐Earth Elements: The Trisbenzene Complexes M(Bz)(3) (M=Sr, Ba)
por: Wang, Qian, et al.
Publicado: (2019)

Alkaline Earth Metals Activate N(2) and CO in Cubic Complexes Just Like Transition Metals: A Conceptual Density Functional Theory and Energy Decomposition Analysis Study
por: Bettens, Tom, et al.
Publicado: (2020)

Metal–CO Bonding in Mononuclear Transition Metal Carbonyl Complexes
por: Frenking, Gernot, et al.
Publicado: (2021)

Highly Coordinated Heteronuclear Calcium–Iron Carbonyl Cation Complexes [CaFe(CO)(n)](+) (n=5–12) with d−d Bonding
por: Jin, Xiaoyang, et al.
Publicado: (2021)

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
por: McWilliams, Sean F., et al.
Publicado: (2015)

Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex
por: Suzuki, Naofumi, et al.
Publicado: (2022)

Chemical Bonding in Homoleptic Carbonyl Cations [M{Fe(CO)(5)}(2)](+) (M=Cu, Ag, Au)
por: Pan, Sudip, et al.
Publicado: (2021)

Cation assisted binding and cleavage of dinitrogen by uranium complexes
por: Jori, Nadir, et al.
Publicado: (2022)

Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex
por: Xin, Xiaoqing, et al.
Publicado: (2022)

Dinitrogen cleavage by a dinuclear uranium(iii) complex
por: Jori, Nadir, et al.
Publicado: (2023)

Stabilization of Linear C(3) by Two Donor Ligands: A Theoretical Study of L‐C(3)‐L (L=PPh(3), NHC(Me), cAAC(Me))
por: Gorantla, Sai Manoj N. V. T., et al.
Publicado: (2020)

Dinitrogen fixation in aphotic oxygenated marine environments
por: Rahav, Eyal, et al.
Publicado: (2013)

The boron–boron triple bond in NHC→B[triple bond, length as m-dash]B←NHC
por: Holzmann, Nicole, et al.
Publicado: (2015)

Tropical carbon sink accelerated by symbiotic dinitrogen fixation
por: Levy-Varon, Jennifer H., et al.
Publicado: (2019)

Dinitrogen Fixation: Rationalizing Strategies Utilizing Molecular Complexes
por: Masero, Fabio, et al.
Publicado: (2020)

(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex
por: van Alten, Richt S., et al.
Publicado: (2020)

Group 6 Hexacarbonyls as Ligands for the Silver Cation: Syntheses, Characterization, and Analysis of the Bonding Compared with the Isoelectronic Group 5 Hexacarbonylates
por: Bohnenberger, Jan, et al.
Publicado: (2020)

A Critical Look at Linus Pauling’s Influence on the Understanding of Chemical Bonding
por: Pan, Sudip, et al.
Publicado: (2021)

Comment on “The oxidation state in low-valent beryllium and magnesium compounds” by M. Gimferrer, S. Danés, E. Vos, C. B. Yildiz, I. Corral, A. Jana, P. Salvador and D. M. Andrada, Chem. Sci. 2022, 13, 6583
por: Pan, Sudip, et al.
Publicado: (2022)

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site
por: Kuriyama, Shogo, et al.
Publicado: (2015)

A Cornucopia of Iridium Nitrogen Compounds Produced from Laser‐Ablated Iridium Atoms and Dinitrogen
por: Stüker, Tony, et al.
Publicado: (2020)

The Valence Orbitals of the Alkaline‐Earth Atoms
por: Fernández, Israel, et al.
Publicado: (2020)

Dinitrogen and Related Chemistry of the Lanthanides: A Review of the Reductive Capture of Dinitrogen, As Well As Mono- and Di-aza Containing Ligand Chemistry of Relevance to Known and Postulated Metal Mediated Dinitrogen Derivatives
por: Gardiner, Michael G., et al.
Publicado: (2010)

Functionalization of N(2) via Formal 1,3‐Haloboration of a Tungsten(0) σ‐Dinitrogen Complex
por: Rempel, Anna, et al.
Publicado: (2020)

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
por: Kuriyama, Shogo, et al.
Publicado: (2016)

Dinitrogen Fixation Is Restricted to the Terminal Heterocysts in the Invasive Cyanobacterium Cylindrospermopsis raciborskii CS-505
por: Plominsky, Álvaro M., et al.
Publicado: (2013)

The Bonding Situation in Metalated Ylides
por: Scharf, Lennart T., et al.
Publicado: (2017)

Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction
por: Schluschaß, Bastian, et al.
Publicado: (2019)

Rhenium‐Mediated Conversion of Dinitrogen and Nitric Oxide to Nitrous Oxide
por: Alig, Lukas, et al.
Publicado: (2021)

Double dative bond between divalent carbon(0) and uranium
por: Su, Wei, et al.
Publicado: (2018)

Synthesis of a rhodium(iii) dinitrogen complex using a calix[4]arene-based diphosphine ligand
por: Emerson-King, Jack, et al.
Publicado: (2023)

DNA Interaction and DNA Cleavage Studies of a New Platinum(II) Complex Containing Aliphatic and Aromatic Dinitrogen Ligands
por: Shahabadi, Nahid, et al.
Publicado: (2011)

The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)
por: Xu, Jian, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_p89a44lo124i3eeg7vgbp189do