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CO‐Induced Dinitrogen Fixation and Cleavage Mediated by Boron

The boron atoms react with carbon monoxide and dinitrogen forming the end‐on bonded NNBCO complex in solid neon or in nitrogen matrices. The NNBCO complex rearranges to the (η (2)‐N(2))BCO isomer with a more activated side‐on bonded dinitrogen ligand upon visible light excitation. (η (2)‐N(2))BCO an...

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Detalles Bibliográficos
Autores principales: Deng, Guohai, Pan, Sudip, Dong, Xuelin, Wang, Guanjun, Zhao, Lili, Zhou, Mingfei, Frenking, Gernot
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898689/
https://www.ncbi.nlm.nih.gov/pubmed/32990332
http://dx.doi.org/10.1002/chem.202004357

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