Cargando…

Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages

Chiral zirconium(IV) double cage sandwich complex Zr(1)(2) has been synthesized in one step from porphyrin cage H(2)1. Zr(1)(2) was obtained as a racemate, which was resolved by HPLC and the enantiomers were isolated in >99.5 % ee. Their absolute configurations were assigned on the basis of X‐ray...

Descripción completa

Detalles Bibliográficos
Autores principales: Bruekers, Jeroen P. J., Hellinghuizen, Matthijs A., Vanthuyne, Nicolas, Tinnemans, Paul, Gilissen, Pieter J., Buma, Wybren Jan, Naubron, Jean‐Valère, Crassous, Jeanne, Elemans, Johannes A. A. W., Nolte, Roeland J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898692/
https://www.ncbi.nlm.nih.gov/pubmed/33679232
http://dx.doi.org/10.1002/ejoc.202001392