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Arrested Substrate Binding Resolves Catalytic Intermediates in Higher‐Plant Water Oxidation
Among the intermediate catalytic steps of the water‐oxidizing Mn(4)CaO(5) cluster of photosystem II (PSII), the final metastable S(3) state is critically important because it binds one substrate and precedes O(2) evolution. Herein, we combine X‐ and Q‐band EPR experiments on native and methanol‐trea...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898718/ https://www.ncbi.nlm.nih.gov/pubmed/33030775 http://dx.doi.org/10.1002/anie.202012304 |