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Arrested Substrate Binding Resolves Catalytic Intermediates in Higher‐Plant Water Oxidation

Among the intermediate catalytic steps of the water‐oxidizing Mn(4)CaO(5) cluster of photosystem II (PSII), the final metastable S(3) state is critically important because it binds one substrate and precedes O(2) evolution. Herein, we combine X‐ and Q‐band EPR experiments on native and methanol‐trea...

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Detalles Bibliográficos
Autores principales: Zahariou, Georgia, Ioannidis, Nikolaos, Sanakis, Yiannis, Pantazis, Dimitrios A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898718/
https://www.ncbi.nlm.nih.gov/pubmed/33030775
http://dx.doi.org/10.1002/anie.202012304