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Dimerization of Linear Butenes and Pentenes in an Acidic Zeolite (H‐MFI)

Quantum chemical evidence is produced to show that dimerization of linear butenes and pentenes at zeolitic Brønsted sites in H‐MFI yields alkanes featuring cyclohexane rings rather than branched alkenes. The absence of any C=C double bond in the formed cyclic alkane explains the observations that ol...

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Detalles Bibliográficos
Autores principales: Berger, Fabian, Sauer, Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898720/
https://www.ncbi.nlm.nih.gov/pubmed/33314606
http://dx.doi.org/10.1002/anie.202013671