Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State

Single‐crystal to single‐crystal solid‐state molecular organometallic (SMOM) techniques are used for the synthesis and structural characterization of the σ‐alkane complex [Rh(tBu(2)PCH(2)CH(2)CH(2)PtBu(2))(η(2),η(2)‐C(7)H(12))][BAr(F) (4)] (Ar(F)=3,5‐(CF(3))(2)C(6)H(3)), in which the alkane (norborn...

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Detalles Bibliográficos
Autores principales: Furfari, Samantha K., Tegner, Bengt E., Burnage, Arron L., Doyle, Laurence R., Bukvic, Alexander J., Macgregor, Stuart A., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898853/
https://www.ncbi.nlm.nih.gov/pubmed/33112000
http://dx.doi.org/10.1002/chem.202004585

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898853/
https://www.ncbi.nlm.nih.gov/pubmed/33112000
http://dx.doi.org/10.1002/chem.202004585

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