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Mechanochemically Triggered Topology Changes in Expanded Porphyrins

A hitherto unexplored class of molecules for molecular force probe applications are expanded porphyrins. This work proves that mechanical force is an effective stimulus to trigger the interconversion between Hückel and Möbius topologies in [28]hexaphyrin, making these expanded porphyrins suitable to...

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Detalles Bibliográficos
Autores principales: Bettens, Tom, Hoffmann, Marvin, Alonso, Mercedes, Geerlings, Paul, Dreuw, Andreas, De Proft, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7898923/
https://www.ncbi.nlm.nih.gov/pubmed/33170967
http://dx.doi.org/10.1002/chem.202003869