Switching Site Reactivity in Hydrogenase Model Systems by Introducing a Pendant Amine Ligand

[Image: see text] Hydrogenases are versatile enzymatic catalysts with an unmet hydrogen evolution reactivity (HER) from synthetic bio-inspired systems. The binuclear active site only has one-site reactivity of the distal Fe(d) atom. Here, binuclear complexes [Fe(2)(CO)(5)(μ-Mebdt)(P(4-C(6)H(4)OCH(3)...

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Detalles Bibliográficos
Autores principales: Pandey, Indresh Kumar, Agarwal, Tashika, Mobin, Shaikh M., Stein, Matthias, Kaur-Ghumaan, Sandeep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7906588/
https://www.ncbi.nlm.nih.gov/pubmed/33644543
http://dx.doi.org/10.1021/acsomega.0c04901

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7906588/
https://www.ncbi.nlm.nih.gov/pubmed/33644543
http://dx.doi.org/10.1021/acsomega.0c04901

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