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Switching Site Reactivity in Hydrogenase Model Systems by Introducing a Pendant Amine Ligand

[Image: see text] Hydrogenases are versatile enzymatic catalysts with an unmet hydrogen evolution reactivity (HER) from synthetic bio-inspired systems. The binuclear active site only has one-site reactivity of the distal Fe(d) atom. Here, binuclear complexes [Fe(2)(CO)(5)(μ-Mebdt)(P(4-C(6)H(4)OCH(3)...

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Detalles Bibliográficos
Autores principales:	Pandey, Indresh Kumar, Agarwal, Tashika, Mobin, Shaikh M., Stein, Matthias, Kaur-Ghumaan, Sandeep
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7906588/ https://www.ncbi.nlm.nih.gov/pubmed/33644543 http://dx.doi.org/10.1021/acsomega.0c04901

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