Tuning π-Acceptor/σ-Donor Ratio of the 2-Isocyanoazulene Ligand: Non-Fluorinated Rival of Pentafluorophenyl Isocyanide and Trifluorovinyl Isocyanide Discovered

Isocyanoazulenes (CNAz) constitute a relatively new class of isocyanoarenes that offers rich structural and electronic diversification of the organic isocyanide ligand platform. This article considers a series of 2-isocyano-1,3-X(2)-azulene ligands (X = H, Me, CO(2)Et, Br, and CN) and the correspond...

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Detalles Bibliográficos
Autores principales: Hart, Mason D., Meyers, John J., Wood, Zachary A., Nakakita, Toshinori, Applegate, Jason C., Erickson, Nathan R., Gerasimchuk, Nikolay N., Barybin, Mikhail V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7918097/
https://www.ncbi.nlm.nih.gov/pubmed/33673291
http://dx.doi.org/10.3390/molecules26040981

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7918097/
https://www.ncbi.nlm.nih.gov/pubmed/33673291
http://dx.doi.org/10.3390/molecules26040981

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