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Structural Characterization of Two CO Molecules Bound to the Nitrogenase Active Site

As an approach towards unraveling the nitrogenase mechanism, we have studied the binding of CO to the active‐site FeMo‐cofactor. CO is not only an inhibitor of nitrogenase, but it is also a substrate, undergoing reduction to hydrocarbons (Fischer–Tropsch‐type chemistry). The C−C bond forming capabil...

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Detalles Bibliográficos
Autores principales: Buscagan, Trixia M., Perez, Kathryn A., Maggiolo, Ailiena O., Rees, Douglas C., Spatzal, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7920927/
https://www.ncbi.nlm.nih.gov/pubmed/33320413
http://dx.doi.org/10.1002/anie.202015751