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Structural Characterization of Two CO Molecules Bound to the Nitrogenase Active Site
As an approach towards unraveling the nitrogenase mechanism, we have studied the binding of CO to the active‐site FeMo‐cofactor. CO is not only an inhibitor of nitrogenase, but it is also a substrate, undergoing reduction to hydrocarbons (Fischer–Tropsch‐type chemistry). The C−C bond forming capabil...
Autores principales: | Buscagan, Trixia M., Perez, Kathryn A., Maggiolo, Ailiena O., Rees, Douglas C., Spatzal, Thomas |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7920927/ https://www.ncbi.nlm.nih.gov/pubmed/33320413 http://dx.doi.org/10.1002/anie.202015751 |
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