New Bifunctional Bis(azairidacycle) with Axial Chirality via Double Cyclometalation of 2,2′-Bis(aminomethyl)-1,1′-binaphthyl

As a candidate for bifunctional asymmetric catalysts containing a half-sandwich C–N chelating Ir(III) framework (azairidacycle), a dinuclear Ir complex with an axially chiral linkage is newly designed. An expedient synthesis of chiral 2,2′-bis(aminomethyl)-1,1′-binaphthyl (1) from 1,1-bi-2-naphthol...

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Detalles Bibliográficos
Autores principales: Sato, Yasuhiro, Kawata, Yuichi, Yasui, Shungo, Kayaki, Yoshihito, Ikariya, Takao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926664/
https://www.ncbi.nlm.nih.gov/pubmed/33671758
http://dx.doi.org/10.3390/molecules26041165

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7926664/
https://www.ncbi.nlm.nih.gov/pubmed/33671758
http://dx.doi.org/10.3390/molecules26041165

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