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A Mononuclear and High-Spin Tetrahedral Ti(II) Complex

[Image: see text] A high-spin, mononuclear Ti(II) complex, [(Tp(tBu,Me))TiCl] [Tp(tBu,Me–) = hydridotris(3-tert-butyl-5-methylpyrazol-1-yl)borate], confined to a tetrahedral ligand-field environment, has been prepared by reduction of the precursor [(Tp(tBu,Me))TiCl(2)] with KC(8). Complex [(Tp(tBu,M...

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Detalles Bibliográficos
Autores principales: Reinholdt, Anders, Pividori, Daniel, Laughlin, Alexander L., DiMucci, Ida M., MacMillan, Samantha N., Jafari, Mehrafshan G., Gau, Michael R., Carroll, Patrick J., Krzystek, J., Ozarowski, Andrew, Telser, Joshua, Lancaster, Kyle M., Meyer, Karsten, Mindiola, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7928263/
https://www.ncbi.nlm.nih.gov/pubmed/33258366
http://dx.doi.org/10.1021/acs.inorgchem.0c02586