Asymmetric Total Synthesis of (+)-21-epi-Eburnamonine Via a Photocatalytic Radical Cascade Reaction

An asymmetric total synthesis of (+)-21-epi-eburnamonine has been achieved. Key features of the synthesis include a visible-light photocatalytic intra-/intramolecular radical cascade reaction to assemble the tetracyclic ABCD ring system, and a highly diastereoselective Johnson-Claisen rearrangement...

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Detalles Bibliográficos
Autores principales: Huang, Yuan, Xue, Fanglin, Liu, Hengmao, Xue, Fei, Liu, Xiao-Yu, Song, Hao, Qin, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Singapore 2020
Materias:
Short Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7933312/
https://www.ncbi.nlm.nih.gov/pubmed/33155164
http://dx.doi.org/10.1007/s13659-020-00276-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7933312/
https://www.ncbi.nlm.nih.gov/pubmed/33155164
http://dx.doi.org/10.1007/s13659-020-00276-8

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