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Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
The E/Z stereocontrol in a C=C bond is a fundamental issue in olefin synthesis. Although the thermodynamically more stable E geometry is readily addressable by thermal Z to E geometric isomerization through equilibrium, it has remained difficult to undergo thermal geometric isomerization to the reve...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7935995/ https://www.ncbi.nlm.nih.gov/pubmed/33674574 http://dx.doi.org/10.1038/s41467-021-21720-4 |