Cargando…

Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism

The E/Z stereocontrol in a C=C bond is a fundamental issue in olefin synthesis. Although the thermodynamically more stable E geometry is readily addressable by thermal Z to E geometric isomerization through equilibrium, it has remained difficult to undergo thermal geometric isomerization to the reve...

Descripción completa

Detalles Bibliográficos
Autores principales:	Kudo, Eiji, Sasaki, Kota, Kawamata, Shiori, Yamamoto, Koji, Murahashi, Tetsuro
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7935995/ https://www.ncbi.nlm.nih.gov/pubmed/33674574 http://dx.doi.org/10.1038/s41467-021-21720-4

Ejemplares similares

Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene
por: Timsina, Yam N., et al.
Publicado: (2014)

Retraction of “Chemoselective Reactions of (E)-1,3-Dienes: Cobalt-Mediated Isomerization to (Z)-1,3-Dienes and Reactions with Ethylene”
por: Timsina, Yam N., et al.
Publicado: (2018)

Soft Propargylic Deprotonation: Designed Ligand Enables Au-Catalyzed Isomerization of Alkynes to 1,3-Dienes
por: Wang, Zhixun, et al.
Publicado: (2014)

Tandem isomerization/telomerization of long chain dienes
por: Torrente-Murciano, Laura, et al.
Publicado: (2014)

Enantioselective Nickel‐Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization
por: Yap, Connor, et al.
Publicado: (2017)

Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole
por: Korff, Marvin, et al.
Publicado: (2022)

Enantioselective Nickel-Catalyzed anti-Carbometallative Cyclizations of Alkynyl Electrophiles Enabled by Reversible Alkenylnickel E/Z Isomerization
por: Clarke, Christopher, et al.
Publicado: (2016)

Proton-Stabilized Photochemically Reversible E/Z Isomerization of Spiropyrans
por: Kortekaas, L., et al.
Publicado: (2018)

Multinuclear metal-binding ability of a carotene
por: Horiuchi, Shinnosuke, et al.
Publicado: (2015)

Palladium Hydride Promoted Stereoselective Isomerization of Unactivated Di(exo)methylenes to Endocyclic Dienes
por: Jung, Michael E., et al.
Publicado: (2014)

(Z,Z)-1,4-Diiodo-1,4-bis(trimethylsilyl)buta-1,3-diene
por: Bats, Jan W., et al.
Publicado: (2008)

New Insights into Acylhydrazones E/Z Isomerization: An Experimental and Theoretical Approach †
por: Fernández-Palacios, Sara, et al.
Publicado: (2023)

1-(Triethoxysilyl)buta-1,3-dienes—New Building Blocks for Stereoselective Synthesis of Unsymmetrical (E,E)-1,4-Disubstituted 1,3-dienes
por: Szudkowska-Frątczak, Justyna, et al.
Publicado: (2015)

Photocatalytic E→Z Contra‐Thermodynamic Isomerization of Vinyl Silanes with Lewis Base
por: Le, Thi Minh Thi, et al.
Publicado: (2022)

Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry
por: Lin, Jieli, et al.
Publicado: (2023)

Isomerization of Functionalized Olefins by Using the Dinuclear Catalyst [Pd(I)(μ‐Br)(P( t )Bu(3))](2): A Mechanistic Study
por: Koley, Debasis, et al.
Publicado: (2021)

Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation
por: Corra, Stefano, et al.
Publicado: (2021)

Singlet and Triplet Pathways Determine the Thermal Z/E Isomerization of an Arylazopyrazole-Based Photoswitch
por: Singer, Nadja K., et al.
Publicado: (2023)

Isomerization enabling near-infrared electron acceptors
por: Luo, Jiasi, et al.
Publicado: (2019)

Convergent Synthesis of Dihydrobenzofurans via Urea Ligand-Enabled Heteroannulation of 2-Bromophenols with 1,3-Dienes
por: Houghtling, Kaitlyn E., et al.
Publicado: (2022)

Solvent-controlled E/Z isomerization vs. [2 + 2] photocycloaddition mediated by supramolecular polymerization
por: Dünnebacke, Torsten, et al.
Publicado: (2020)

(Z)-α-Boryl-crotylboron reagents via Z-selective alkene isomerization and application to stereoselective syntheses of (E)-δ-boryl-syn-homoallylic alcohols
por: Gao, Shang, et al.
Publicado: (2019)

Membrane Environment Enables Ultrafast Isomerization of Amphiphilic Azobenzene
por: Paternò, Giuseppe Maria, et al.
Publicado: (2020)

Copolymerization of epoxides with cyclic anhydrides catalyzed by dinuclear cobalt complexes
por: Hiranoi, Yo, et al.
Publicado: (2018)

Isomeric 13/2$^+$ state in $^{201}$Fr
por: Auranen, K, et al.
Publicado: (2020)

Potential energy of dinuclear system
por: Adamian, G G, et al.
Publicado: (1993)

Mass parameters for dinuclear system
por: Adamian, G G, et al.
Publicado: (1993)

Rat intestinal homogenate and pancreatic juice can induce the Z-isomerization of all-E-lycopene in vitro
por: Huang, Jin, et al.
Publicado: (2020)

E–Z isomerization of 3-benzylidene-indolin-2-ones using a microfluidic photo-reactor
por: Raji Reddy, Chada, et al.
Publicado: (2020)

Probing E/Z Isomerism Using Pillar[4]pyridinium/Gold Nanoparticle Ensembles and Their Photoresponsive Behavior
por: Kravets, Mykola, et al.
Publicado: (2022)

Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis
por: Chen, Qing-An, et al.
Publicado: (2014)

Cobalt-catalysed asymmetric hydrovinylation of 1,3-dienes
por: Timsina, Yam N., et al.
Publicado: (2015)

Ni-Catalyzed Enantioselective Hydrofunctionalizations of 1,3-Dienes
por: Flaget, Arthur, et al.
Publicado: (2022)

Nickel-catalyzed regio- and enantio-selective Markovnikov hydromonofluoroalkylation of 1,3-dienes
por: Liao, Ling, et al.
Publicado: (2022)

Base-catalyzed aryl halide isomerization enables the 4-selective substitution of 3-bromopyridines
por: Puleo, Thomas R., et al.
Publicado: (2020)

Mechanistic aspects of the isomerization of Z-vinylic tellurides double bonds in the synthesis of potassium Z-vinyltrifluoroborate salts
por: Stefani, Hélio A, et al.
Publicado: (2008)

Dinuclear complex-induced DNA melting
por: Biere, Niklas, et al.
Publicado: (2023)

Synthesis and structures of dinuclear palladium complexes with 1,3-benzimidazolidine-2-thione and 1,3-imidazoline-2-thione
por: Lobana, Tarlok S., et al.
Publicado: (2023)

Nickel-catalyzed hydroalkylation and hydroalkenylation of 1,3-dienes with hydrazones
por: Cheng, Lei, et al.
Publicado: (2019)

Modern Synthetic Methods for the Stereoselective Construction of 1,3-Dienes
por: Soengas, Raquel G., et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_pii4llah6raaf73t14nlfcjr3m