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(NH(4))Mg(HSO(4))(SO(4))(H(2)O)(2) and NaSc(CrO(4))(2)(H(2)O)(2), two crystal structures com­prising kröhnkite-type chains, and the temperature-induced phase transition (NH(4))Mg(HSO(4))(SO(4))(H(2)O)(2) [Image: see text] (NH(4))MgH(SO(4))(2)(H(2)O)(2)

The crystal structure of the mineral kröhnkite, Na(2)Cu(SO(4))(2)(H(2)O)(2), contains infinite chains com­posed of [CuO(4)(OH(2))(2)] octa­hedra corner-linked with SO(4) tetra­hedra. Such or similar tetra­hedral–octa­hedral ‘kröhnkite-type’ chains are present in the crystal structures of numerous co...

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Detalles Bibliográficos
Autores principales: Weil, Matthias, Kolitsch, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7941265/
https://www.ncbi.nlm.nih.gov/pubmed/33664165
http://dx.doi.org/10.1107/S2053229621001650