Octahedral Trifluoromagnesate, an Anomalous Metal Fluoride Species, Stabilizes the Transition State in a Biological Motor

[Image: see text] Isoelectronic metal fluoride transition state analogue (TSA) complexes, MgF(3)(–) and AlF(4)(–), have proven to be immensely useful in understanding mechanisms of biological motors utilizing phosphoryl transfer. Here we report a previously unobserved octahedral TSA complex, MgF(3)(...

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Detalles Bibliográficos
Autores principales: Ge, Mengyu, Molt, Robert W., Jenkins, Huw T., Blackburn, G. Michael, Jin, Yi, Antson, Alfred A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7944477/
https://www.ncbi.nlm.nih.gov/pubmed/33717640
http://dx.doi.org/10.1021/acscatal.0c04500

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7944477/
https://www.ncbi.nlm.nih.gov/pubmed/33717640
http://dx.doi.org/10.1021/acscatal.0c04500

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