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Octahedral Trifluoromagnesate, an Anomalous Metal Fluoride Species, Stabilizes the Transition State in a Biological Motor
[Image: see text] Isoelectronic metal fluoride transition state analogue (TSA) complexes, MgF(3)(–) and AlF(4)(–), have proven to be immensely useful in understanding mechanisms of biological motors utilizing phosphoryl transfer. Here we report a previously unobserved octahedral TSA complex, MgF(3)(...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7944477/ https://www.ncbi.nlm.nih.gov/pubmed/33717640 http://dx.doi.org/10.1021/acscatal.0c04500 |