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Coordination-induced polymerization of P═C bonds leads to regular (P─C)(n) polycarbophosphanes

The replacement of carbon in (C─C)(n) chains of polyolefins by phosphorus leads to polycarbophosphanes (P─C)(n), which may possess unique chemical and physical properties. However, macromolecules with a regular (P─C)(n) chain have never been unambiguously identified. Here, we demonstrate that additi...

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Detalles Bibliográficos
Autores principales: Mei, Yanbo, Gamboa-Carballo, Juan José, Bao, Yinyin, Wu, Na, Le Corre, Grégoire, Grützmacher, Hansjörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7946365/
https://www.ncbi.nlm.nih.gov/pubmed/33692112
http://dx.doi.org/10.1126/sciadv.abf4272