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Mechanistic Investigations of Ruthenium Catalyzed Dehydrogenative Thioester Synthesis and Thioester Hydrogenation

[Image: see text] We have recently reported the previously unknown synthesis of thioesters by coupling thiols and alcohols (or aldehydes) with liberation of H(2), as well as the reverse hydrogenation of thioesters, catalyzed by a well-defined ruthenium acridine-9H based pincer complex. These reactio...

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Detalles Bibliográficos
Autores principales: Rauch, Michael, Luo, Jie, Avram, Liat, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7976608/
https://www.ncbi.nlm.nih.gov/pubmed/33763290
http://dx.doi.org/10.1021/acscatal.1c00418