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Non‐Planar Structures of Sterically Overcrowded Trialkylamines

Several amines with three bulky alkyl groups at the nitrogen atom, which exceed the steric crowding of triisopropylamine significantly, were synthesized, mainly by treating N‐chlorodialkylamines with Grignard reagents. In six cases, namely tert‐butyldiisopropylamine, 1‐adamantyl‐tert‐butylisopropyla...

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Detalles Bibliográficos
Autores principales: Banert, Klaus, Heck, Manuel, Ihle, Andreas, Shoker, Tharallah, Wörle, Michael, Boese, A. Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7984391/
https://www.ncbi.nlm.nih.gov/pubmed/32914915
http://dx.doi.org/10.1002/chem.202003933