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Non‐Planar Structures of Sterically Overcrowded Trialkylamines
Several amines with three bulky alkyl groups at the nitrogen atom, which exceed the steric crowding of triisopropylamine significantly, were synthesized, mainly by treating N‐chlorodialkylamines with Grignard reagents. In six cases, namely tert‐butyldiisopropylamine, 1‐adamantyl‐tert‐butylisopropyla...
Autores principales: | Banert, Klaus, Heck, Manuel, Ihle, Andreas, Shoker, Tharallah, Wörle, Michael, Boese, A. Daniel |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7984391/ https://www.ncbi.nlm.nih.gov/pubmed/32914915 http://dx.doi.org/10.1002/chem.202003933 |
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