A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions

S=2 oxoiron(IV) species act as reactive intermediates in the catalytic cycle of nonheme iron oxygenases. The few available synthetic S=2 Fe(IV)=O complexes known to date are often limited to trigonal bipyramidal and very rarely to octahedral geometries. Herein we describe the generation and characte...

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Detalles Bibliográficos
Autores principales: Warm, Katrin, Paskin, Alice, Kuhlmann, Uwe, Bill, Eckhard, Swart, Marcel, Haumann, Michael, Dau, Holger, Hildebrandt, Peter, Ray, Kallol
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7985879/
https://www.ncbi.nlm.nih.gov/pubmed/33348460
http://dx.doi.org/10.1002/anie.202015896

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7985879/
https://www.ncbi.nlm.nih.gov/pubmed/33348460
http://dx.doi.org/10.1002/anie.202015896

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