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Synthesis of Unprecedented 4d/4f‐Polypnictogens

A series of 4d/4f‐polyarsenides, ‐polyarsines and ‐polystibines was obtained by reduction of the Mo‐pnictide precursor complexes [{Cp(t)Mo(CO)(2)}(2)(μ,η (2:2)‐E(2))] (E=As, Sb; Cp(t)=tBu substituted cyclopentadienyl) with two different divalent samarocenes [Cp*(2)Sm] and [(Cp(Me4nPr))(2)Sm]. For th...

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Detalles Bibliográficos
Autores principales: Reinfandt, Niklas, Schoo, Christoph, Dütsch, Luis, Köppe, Ralf, Konchenko, Sergey N., Scheer, Manfred, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986065/
https://www.ncbi.nlm.nih.gov/pubmed/33010187
http://dx.doi.org/10.1002/chem.202003905