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Exploring the Reactivity of a Frustrated Sn/P Lewis Pair: The Highly Selective Complexation of the cis‐Azobenzene Photoisomer

The reactivity of the geminal frustrated Lewis pair (FLP) (F(5)C(2))(3)SnCH(2)P(tBu)(2) (1) was explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH, H(3)CC(O)CH=CH(2), Ph[C(O)](2)Ph, PhN=NPh and Me(3)SiCHN(2)), featuring polar or non‐polar multiple bonds and/or rep...

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Detalles Bibliográficos
Autores principales: Holtkamp, Philipp, Poier, Dario, Neumann, Beate, Stammler, Hans‐Georg, Mitzel, Norbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986075/
https://www.ncbi.nlm.nih.gov/pubmed/33284497
http://dx.doi.org/10.1002/chem.202004600