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Generation and Characterization of the C(3)O(2) (−) Anion with an Unexpected Unsymmetrical Structure
The carbon suboxide anion C(3)O(2) (−) is generated in solid neon matrix. It is characterized by infrared absorption spectroscopy as well as quantum chemical calculations to have a planar C (s) structure where two CO groups with significantly different bond lengths and angles are attached in a zigza...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986081/ https://www.ncbi.nlm.nih.gov/pubmed/33210794 http://dx.doi.org/10.1002/anie.202013921 |