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Generation and Characterization of the C(3)O(2) (−) Anion with an Unexpected Unsymmetrical Structure
The carbon suboxide anion C(3)O(2) (−) is generated in solid neon matrix. It is characterized by infrared absorption spectroscopy as well as quantum chemical calculations to have a planar C (s) structure where two CO groups with significantly different bond lengths and angles are attached in a zigza...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986081/ https://www.ncbi.nlm.nih.gov/pubmed/33210794 http://dx.doi.org/10.1002/anie.202013921 |
| _version_ | 1783668371087163392 |
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| author | Wang, Lina Pan, Sudip Lu, Bo Dong, Xuelin Li, Hongmin Deng, Guohai Zeng, Xiaoqing Zhou, Mingfei Frenking, Gernot |
| author_facet | Wang, Lina Pan, Sudip Lu, Bo Dong, Xuelin Li, Hongmin Deng, Guohai Zeng, Xiaoqing Zhou, Mingfei Frenking, Gernot |
| author_sort | Wang, Lina |
| collection | PubMed |
| description | The carbon suboxide anion C(3)O(2) (−) is generated in solid neon matrix. It is characterized by infrared absorption spectroscopy as well as quantum chemical calculations to have a planar C (s) structure where two CO groups with significantly different bond lengths and angles are attached in a zigzag fashion to the central carbon atom. Bonding analysis indicates that it is best described by the bonding interactions between a neutral CO in a triplet excited state and a doublet excited state of CCO(−). |
| format | Online Article Text |
| id | pubmed-7986081 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-79860812021-03-25 Generation and Characterization of the C(3)O(2) (−) Anion with an Unexpected Unsymmetrical Structure Wang, Lina Pan, Sudip Lu, Bo Dong, Xuelin Li, Hongmin Deng, Guohai Zeng, Xiaoqing Zhou, Mingfei Frenking, Gernot Angew Chem Int Ed Engl Communications The carbon suboxide anion C(3)O(2) (−) is generated in solid neon matrix. It is characterized by infrared absorption spectroscopy as well as quantum chemical calculations to have a planar C (s) structure where two CO groups with significantly different bond lengths and angles are attached in a zigzag fashion to the central carbon atom. Bonding analysis indicates that it is best described by the bonding interactions between a neutral CO in a triplet excited state and a doublet excited state of CCO(−). John Wiley and Sons Inc. 2021-01-12 2021-02-23 /pmc/articles/PMC7986081/ /pubmed/33210794 http://dx.doi.org/10.1002/anie.202013921 Text en © 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
| spellingShingle | Communications Wang, Lina Pan, Sudip Lu, Bo Dong, Xuelin Li, Hongmin Deng, Guohai Zeng, Xiaoqing Zhou, Mingfei Frenking, Gernot Generation and Characterization of the C(3)O(2) (−) Anion with an Unexpected Unsymmetrical Structure |
| title | Generation and Characterization of the C(3)O(2)
(−) Anion with an Unexpected Unsymmetrical Structure |
| title_full | Generation and Characterization of the C(3)O(2)
(−) Anion with an Unexpected Unsymmetrical Structure |
| title_fullStr | Generation and Characterization of the C(3)O(2)
(−) Anion with an Unexpected Unsymmetrical Structure |
| title_full_unstemmed | Generation and Characterization of the C(3)O(2)
(−) Anion with an Unexpected Unsymmetrical Structure |
| title_short | Generation and Characterization of the C(3)O(2)
(−) Anion with an Unexpected Unsymmetrical Structure |
| title_sort | generation and characterization of the c(3)o(2)
(−) anion with an unexpected unsymmetrical structure |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986081/ https://www.ncbi.nlm.nih.gov/pubmed/33210794 http://dx.doi.org/10.1002/anie.202013921 |
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