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Reductive Coupling of (Fluoro)pyridines by Linear 3d‐Metal(I) Silylamides of Cr–Co: A Tale of C−C Bond Formation, C−F Bond Cleavage and a Pyridyl Radical Anion
Herein, we disclose the facile reduction of pyridine (and its derivatives) by linear 3d‐metal(I) silylamides (M=Cr–Co). This reaction resulted in intermolecular C−C coupling to give dinuclear metal(II) complexes bearing a bridging 4,4′‐dihydrobipyridyl ligand. For iron, we demonstrated that the C−C...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986091/ https://www.ncbi.nlm.nih.gov/pubmed/33453071 http://dx.doi.org/10.1002/chem.202004852 |