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Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)

The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. Th...

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Detalles Bibliográficos
Autores principales: Jung, Jochen, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986191/
https://www.ncbi.nlm.nih.gov/pubmed/33480147
http://dx.doi.org/10.1002/anie.202014426