Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)

The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. Th...

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Autores principales: Jung, Jochen, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986191/
https://www.ncbi.nlm.nih.gov/pubmed/33480147
http://dx.doi.org/10.1002/anie.202014426
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author Jung, Jochen
Münch, Annika
Herbst‐Irmer, Regine
Stalke, Dietmar
author_facet Jung, Jochen
Münch, Annika
Herbst‐Irmer, Regine
Stalke, Dietmar
author_sort Jung, Jochen
collection PubMed
description The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. The easy‐to‐polarize S−N bonds are an advantageous and versatile feature of sulfur nitrogen ligands, which enables them to adapt to different electron requirements of various metal cations.
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spelling pubmed-79861912021-03-25 Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4) Jung, Jochen Münch, Annika Herbst‐Irmer, Regine Stalke, Dietmar Angew Chem Int Ed Engl Communications The valence isoelectronic imido analog H(2)S(NtBu)(4) (1) of sulfuric acid H(2)SO(4) was synthesized, isolated, and characterized by NMR spectroscopy and high‐resolution X‐ray charge density analysis. The latter reveals strongly polarized S(δ+)−N(δ−) bonds with virtually no double bond character. The easy‐to‐polarize S−N bonds are an advantageous and versatile feature of sulfur nitrogen ligands, which enables them to adapt to different electron requirements of various metal cations. John Wiley and Sons Inc. 2021-01-28 2021-03-08 /pmc/articles/PMC7986191/ /pubmed/33480147 http://dx.doi.org/10.1002/anie.202014426 Text en © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Jung, Jochen
Münch, Annika
Herbst‐Irmer, Regine
Stalke, Dietmar
Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title_full Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title_fullStr Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title_full_unstemmed Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title_short Tetraimido Sulfuric Acid H(2)S(NtBu)(4)—Valence Isoelectronic to H(2)SO(4)
title_sort tetraimido sulfuric acid h(2)s(ntbu)(4)—valence isoelectronic to h(2)so(4)
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986191/
https://www.ncbi.nlm.nih.gov/pubmed/33480147
http://dx.doi.org/10.1002/anie.202014426
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AT herbstirmerregine tetraimidosulfuricacidh2sntbu4valenceisoelectronictoh2so4
AT stalkedietmar tetraimidosulfuricacidh2sntbu4valenceisoelectronictoh2so4

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