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Activation of Di‐tert‐butyldiphosphatetrahedrane: Access to (tBuCP)(n) (n=2, 4) Ligand Frameworks by P−C Bond Cleavage
The first mixed phosphatetrahedranes were reported only recently and their reactivity is virtually unexplored. Herein, we present a reactivity study on di‐tert‐butyldiphosphatetrahedrane (1), which is the dimer of tert‐butylphosphaalkyne. The (tBuCP)(2) tetrahedron is activated selectively by N‐hete...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986217/ https://www.ncbi.nlm.nih.gov/pubmed/33403771 http://dx.doi.org/10.1002/anie.202015680 |