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Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)

The controlled release of well‐defined radical species under mild conditions for subsequent use in selective reactions is an important and challenging task in synthetic chemistry. We show here that simple bismuth amide species [Bi(NAr(2))(3)] readily release aminyl radicals [NAr(2)](.) at ambient te...

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Detalles Bibliográficos
Autores principales: Oberdorf, Kai, Hanft, Anna, Ramler, Jacqueline, Krummenacher, Ivo, Bickelhaupt, F. Matthias, Poater, Jordi, Lichtenberg, Crispin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986226/
https://www.ncbi.nlm.nih.gov/pubmed/33315293
http://dx.doi.org/10.1002/anie.202015514