Oxidation Under Reductive Conditions: From Benzylic Ethers to Acetals with Perfect Atom‐Economy by Titanocene(III) Catalysis

Described here is a titanocene‐catalyzed reaction for the synthesis of acetals and hemiaminals from benzylic ethers and benzylic amines, respectively, with pendant epoxides. The reaction proceeds by catalysis in single‐electron steps. The oxidative addition comprises an epoxide opening. An H‐atom tr...

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Detalles Bibliográficos
Autores principales: Funk, Pierre, Richrath, Ruben B., Bohle, Fabian, Grimme, Stefan, Gansäuer, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986230/
https://www.ncbi.nlm.nih.gov/pubmed/33245820
http://dx.doi.org/10.1002/anie.202013561

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986230/
https://www.ncbi.nlm.nih.gov/pubmed/33245820
http://dx.doi.org/10.1002/anie.202013561

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