Highly Colored Boron‐Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates

Reduction of (CAAC)BBr(2)(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z‐isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)‐stabilized, boron‐doped, aromatic thiazolothi...

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Detalles Bibliográficos
Autores principales: Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Hermann, Alexander, Brückner, Tobias, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986239/
https://www.ncbi.nlm.nih.gov/pubmed/33492727
http://dx.doi.org/10.1002/anie.202015508

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986239/
https://www.ncbi.nlm.nih.gov/pubmed/33492727
http://dx.doi.org/10.1002/anie.202015508

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