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Base‐Free Pd‐Catalyzed C−Cl Borylation of Fluorinated Aryl Chlorides
Catalytic C−X borylation of aryl halides containing two ortho‐fluorines has been found to be challenging, as most previous methods require stoichiometric amounts of base and the polyfluorinated aryl boronates suffer from protodeboronation, which is accelerated by ortho‐fluorine substituents. Herein,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986610/ https://www.ncbi.nlm.nih.gov/pubmed/33197081 http://dx.doi.org/10.1002/chem.202004648 |