Coordination Behavior of a P(4)‐Butterfly Complex towards Transition Metal Lewis Acids: Preservation versus Rearrangement

The reactivity of the P(4) butterfly complex [{Cp’’’Fe(CO)(2)}(2)(μ,η(1:1)‐P(4))] (1, Cp’’’=η(5)‐C(5)H(2) tBu(3)) towards divalent Co, Ni and Zn salts is investigated. The reaction with the bromide salts leads to [{Cp’’’Fe(CO)(2)}(2)(μ(3),η(2:1:1)‐P(4)){MBr(2)}] (M=Co (2Co), Ni (2Ni), Zn (2Zn)) in w...

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Detalles Bibliográficos
Autores principales: Müller, Julian, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986619/
https://www.ncbi.nlm.nih.gov/pubmed/33314380
http://dx.doi.org/10.1002/chem.202005025

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986619/
https://www.ncbi.nlm.nih.gov/pubmed/33314380
http://dx.doi.org/10.1002/chem.202005025

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