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Coordination Behavior of a P(4)‐Butterfly Complex towards Transition Metal Lewis Acids: Preservation versus Rearrangement
The reactivity of the P(4) butterfly complex [{Cp’’’Fe(CO)(2)}(2)(μ,η(1:1)‐P(4))] (1, Cp’’’=η(5)‐C(5)H(2) tBu(3)) towards divalent Co, Ni and Zn salts is investigated. The reaction with the bromide salts leads to [{Cp’’’Fe(CO)(2)}(2)(μ(3),η(2:1:1)‐P(4)){MBr(2)}] (M=Co (2Co), Ni (2Ni), Zn (2Zn)) in w...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986619/ https://www.ncbi.nlm.nih.gov/pubmed/33314380 http://dx.doi.org/10.1002/chem.202005025 |