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A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis
An I(I)/(III) catalysis strategy to construct an enantioenriched fluorinated isostere of the (i)Pr group is reported. The difluorination of readily accessible α‐CF(3)‐styrenes is enabled by the in situ generation of a chiral ArIF(2) species to forge a stereocentre with the substituents F, CH(2)F and...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986799/ https://www.ncbi.nlm.nih.gov/pubmed/33427355 http://dx.doi.org/10.1002/anie.202015946 |