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Controlling Spin‐Correlated Radical Pairs with Donor–Acceptor Dyads: A New Concept to Generate Reduced Metal Complexes for More Efficient Photocatalysis
One‐electron reduced metal complexes derived from photoactive ruthenium or iridium complexes are important intermediates for substrate activation steps in photoredox catalysis and for the photocatalytic generation of solar fuels. However, owing to the heavy atom effect, direct photochemical pathways...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986886/ https://www.ncbi.nlm.nih.gov/pubmed/33274791 http://dx.doi.org/10.1002/chem.202004638 |