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Highly Active Cooperative Lewis Acid—Ammonium Salt Catalyst for the Enantioselective Hydroboration of Ketones

Enantiopure secondary alcohols are fundamental high‐value synthetic building blocks. One of the most attractive ways to get access to this compound class is the catalytic hydroboration. We describe a new concept for this reaction type that allowed for exceptional catalytic turnover numbers (up to 15...

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Detalles Bibliográficos
Autores principales: Titze, Marvin, Heitkämper, Juliane, Junge, Thorsten, Kästner, Johannes, Peters, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986937/
https://www.ncbi.nlm.nih.gov/pubmed/33210781
http://dx.doi.org/10.1002/anie.202012796